Accepted Answer. It is not possible to play as Princess Peach in New Super Mario Bros. Wii. Player 1 is restricted to playing as Mario, and any subsequent players can choose to play as either Luigi, Blue Toad or Yellow Toad respectively. StrictNebula ( Expert ) - 2 years ago - report.
A follow-up to New Super Mario Bros., named New Super Mario Bros. Wii was released to the Wii in November 2009. It features multiplayer using Luigi and two unnamed Toads. Players control their characters using the Wii Remote like an NES controller. Also new to the game is Yoshi and the return of the Koopalings from Super Mario Bros. 3.The video game New Super Mario Bros. Wii has teamwork and individual competition elements. Players can pick each other up and carry them to safety or dump them into a problematic situation. It is possible to take control of Mario, Luigi, and two Toads, in addition to the many other citizens of the Mushroom Kingdom that make cameo appearances
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